Perfluorooctanesulfonic acid

PFOS, Heptadecafluorooctanesulfonic acid; formula: C8HF17O3S; CAS Registry Number: 1763-23-1
Structure of perfluorooctanesulfonic acid  (PFOS)
Source: PubChem
Identifier: CID 74483
URL: https://pubchem.ncbi.nlm.nih.gov/compound/74483#section=2D-Structure

Fluorocarbon with 8 C-atoms and one sulfonic acid group

Perfluorooctanesulfonic acid (PFOS) is a fluorosurfactant with a nonpolar fully fluorinated C-chain and a polar sulfonic group. It is widely used for impregnation of textiles, leather and paper and is a component of polishes, paints, varnishes, cleaning agents and hydraulic fluids used in aerospace industry. Furthermore, it is used in metal working and photochemistry. PFOS was the key ingredient in Scotchgard™ surface protection products produced by 3M. Together with perfluorooctanoic acid (PFOA) it was a major component of the AFFF-fire-fighting foams (aqueous film forming foam).
During production and use PFOS may enter the environment. It is highly persistent and may spread in the environment reaching even remote areas like the Arctic and Antarctica. PFOS has a high potential for bioaccumulation and can magnify in the food web. It is toxic and suspected to be carcinogenic and reproductive toxic. In the aquatic environment, PFOS may cause long-term adverse effects.

Because of these unfavourable properties, the primary producer 3M has declared a voluntarily phase-out in production of PFOS by 2001. Since 2008, the use of PFOS is restricted in the EU, and in 2009 PFOS and its salts as well as perfluorooctanesulfonyl fluoride (PFOSF) were included in Annex B of the Stockholm Convention (restriction of production and usage).

Specimen

Sampling area

Sampling period

1982 - 2022

Extended information

Links to external information and legislation

Literature