Hexabromocyclododecane
Identifier: CID 18529
URL: https://pubchem.ncbi.nlm.nih.gov/compound/18529#section=2D-Structure
Brominated flame retardant in polystyrene foams and other plastics
Hexabromocyclododecane (HBCD) is a very effective flame retardant. It is mainly used in expanded and extruded polystyrene foams (EPS and XPS) which are used as thermal insulation foams in the construction sector. Furthermore, HBCD is applied in HIPS (high impact polystyrene) used for instance in the housing of electrical and electronic devices and in back-coating of textiles, e.g. in upholstery and car textiles.
As additive flame retardant HBCD it is not chemically bound to the plastic matrix.
Sixteen different stereoisomers of HBCD exist but only the diastereomers α-HBCD, β-HBCD, and γ-HBCD are found in relevant amounts in technical HBCD. Each of these are pairs of enatiomers (mirror images of each other), designated as (+) and (-).
HBCD enters the environment mainly through releases from textile coatings whereas releases during production and from polystyrene foams and HIPS are assumed to be relatively low.
Traces of HBCD are detected in all environmental compartments. Through long range transport it even reaches remote areas like alpine lakes.
HBCD is relative persistent in the environment and toxic to aquatic organisms. Furthermore, it has a very high potential for bioaccumulation and biomagnification.
Because of these properties it was classified as SVHC (substance of very high concern) in the context of the REACh evaluation (Registration, Evaluation, Authorisation and Restriction of Chemicals). Furthermore, it is a candidate for listing under the Stockholm Convention.
However, so far no alternative to HBCD in its major applications exists. Therefore HBCD is used further despite its unfavourable properties.
Substances
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alpha-HBCDSum of (+)- und (-)-α-HBCD (pair of enantiomers). Minor component of technical HBCD (1–12%). In biota the levels of α-HBCD are normally much higher compared to those of β- und γ-HBCD.
Specimen
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Common mussel species as invasive animal in rivers and lakes with high information level for water pollution
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Bioindicator in rivers and lakes
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Fine insoluble mineral or organic particles in the water phase
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One of the most important edible mussel species common in the North and Baltic Sea
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As the only viviparous fish in German nearshore waters, it is a bioindicator in nearshore coastal marine ecosystems.
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Inshore, the herring gull mainly feeds from the sea: upon fish, mussels, and crabs.
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A major primary producer in semi-natural and anthropogenic affected ecosystems.
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The roe deer is the most common of the larger herbivores (first order-consumer) to be found in the wild in Europe.
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Student groups with an even number of female and male students at the age of 20 to 29.
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Sampling area
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The only high mountains national park in Germany and an area of the Limestone Alps with international relevance
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Important, old-industrialised conurbation in Germany.
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Main water divide between the North- and Baltic Sea
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Longest river in Germany
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Germany's first national park
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National Park in the largest brackish water (Bodden) habitat of the world.
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National park in the world largest connected sand and mud flats.
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Fourth largest river basin in Central Europe
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Region in the chemical triangle of Central Germany
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Germany's largest forest national park
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Second highest and largest low mountain range in Northern Germany
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Germany's largest connected forest area in a range of low mountains
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The Upper Bavarian Tertiary Uplands are a part of the Southern German Molasse Basin
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Second largest river in Europe
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4 university cities as sampling areas.
Sampling period
1986 - 2019
Extended information
Links to external information and legislation
- HBCDD EQS dossier 2011 (PDF, external source) (external)
- ECHA 2010: Committee for Risk Assessment RAC: Annex 1: Background Document to the Opinion proposing harmonised classification and labelling at Community level of Hexabromocyclododecane (HBCDD). ECHA/RAC/CLH_O-0000001050-94-03/A1. pp. 70 (PDF, external source) (external)
- ECHA Annex XV dossier: Proposal for identification of a substance as a CMR CAT 1 or 2, PBT, vPvB or substance of an equivalent level of concern. Proposal for identification of Hexabromocyclododecane as a SVHC. (external)
- ECHA-Report 2009: Data on manufacture, import, export, uses and releases of HBCDD as well as information on potential alternatives to its use. ECHA/2008/2 HBCDD Report, pp. 108 (PDF, external source) (external)
Literature
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Temporal trend (1988-2008) of hexabromocyclododecane enantiomers in herring gull eggs from the german coastal region
Esslinger, Susanne; Becker, Roland; Jung, Christian; Schröter-Kermani, Christa; Bremser, Wolfram; Nehl, Irene
Chemosphere 83 (2011), 2, 161-167, 2011